Download/Embed scientific diagram | Diagrama de Pourbaix del hierro [12] y voltaje en función del pH (línea azul). from publication: Síntesis de nanopartículas. Download scientific diagram | Diagrama de Pourbaix para especies de cloro considerando una [Cl-] TOT = mM a T = 25°C para la ferrita de manganeso . ESPECIE. ΔG° (cal/mol). Pb. 0. PbO. , Pb3O4. , Pb2O3. , PbO2. , Pb2+. -5, Pb4+. 72, H2O. , REACCIONES DE.

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There are three types of line boundaries in a Pourbaix diagram: Similarly to phase diagrams, they do not allow for reaction rate or kinetic effects.

Views Read Edit View history. In the Pourbaix diagram for uranium, the limits of stability of water are marked by the two dashed green lines, and the stability region for water falls between these lines. The equation must be diagraas for M, H, O and charge. Geological Survey water-Supply Paper While such diagrams can be drawn for any chemical system, it is important to note that the addition of a metal binding agent ligand will often modify the diagram.

They thus give a guide to the stability of a particular metal in a specific environment. The reaction equation may be written:. As a function of temperature.

Diagrama de Pourbaix – Wikipédia, a enciclopédia livre

Environmental Chemistry – a global perspective 3rd ed. Wikimedia Commons has media related to Pourbaix diagrams.

The presence of trace amounts of certain species such as chloride ions can also greatly affect the stability of ;ourbaix species by destroying passivating layers. Using the Nernst equation as above, but with an Doagramas 0 of 1. For the simple case of a thermodynamic system consisting of a metal M and water, various reaction equations may be written having the form:.

Pourbaix diagrams are widely used to describe the chemical behaviour of chemical species in the hydrosphere. Archived from the original on This page was last edited on 26 Decemberat Archived copy as title Commons category link is on Wikidata.


The reaction equation is written:. Pourbaix diagrams are also known as E H -pH diagrams due pourvaix the labeling of the two axes.

The reaction equation is:.

The lines in the Pourbaix diagram show the equilibrium conditions, that is, where the activities are equal, for the species on each side of that line.

Vertical, horizontal, and sloped. A simplified Pourbaix diagram indicates regions of “Immunity”, “Corrosion” and “Passivity”, instead of the stable species.

Retrieved from ” https: See diagrams at right. From Wikipedia, the free encyclopedia.

Diagrama de Pourbaix

Pourbaix diagrams have several uses, for example in corrosion studies, geoscience and in environmental studies. Predominant ion boundaries are represented by lines.

Immunity means that the metal is not attacked, while corrosion shows that general attack will occur. Using the expressions for the free energy in terms of potentials, the energy balance is given by a Nernst equation:. Usually, the activity of a species is approximated as equal to the concentration for soluble species or partial pressure for gases. This will vary with temperature.

The vertical axis is labeled E H for the voltage potential with respect to the standard hydrogen electrode SHE as calculated by the Nernst equation. The reaction equation is found to be:. On either side of the line, one form of the species will instead be said to be predominant.

In these cases, pE is used instead of E H. Below this line, water will be reduced to hydrogen, and it will usually not be possible to pass beyond this line as long as there is still water present to be reduced. In order to draw the position of the lines with the Nernst equation, the activity of the chemical species at equilibrium must be defined.


Pourbaix diagram – Wikipedia

United States Government Printing Office. As such a Pourbaix diagram can be read much like a standard phase diagram with a different set of axes. The same values should diagramad used for all species present in the system. Using the Pourbaix diagram correctly will help shed light not only on the nature of the species present in the solution or sample but may also help to understand the reaction mechanism. The “H” stands for hydrogen, although other standards may be used, and they are for room temperature only.

Passivation occurs when the metal forms a stable coating of an oxide or other salt on its surface, the best example being the relative stability of aluminium because of the alumina layer formed on its surface when exposed to air. In poubraix cases, the possible conditions in a system are limited by the stability region of water.

Pourbaix diagram

Sometimes additional lines are drawn for other concentrations. In addition, changes in temperature and concentration of ciagramas ions in solution will shift the equilibrium lines in accordance with the Nernst equation. For instance, carbonate has a great effect upon the diagram for uranium. By using this site, you agree to the Terms of Use and Privacy Policy.

The diagrams are named after Marcel Pourbaix —the Russian -born, Belgian chemist who invented them. The diagrams also do not take kinetic effects into account, meaning that species shown as unstable might not react to any significant degree in practice.